The invention is a method for sensing the H₂ concentration of a gaseous stream through evaluation of the optical signal of a hydrogen sensing material comprised of Pd- or Pt-based nanoparticles dispersed in a matrix material. The sensing layers can also include engineered filter layers as the matrix or as an additional layer to improve H₂ selectivity. This technology is available for licensing and/or further collaborative research from the U.S. Department of Energy’s National Energy Technology Laboratory.

Challenge
The ability to selectively sense H₂ is critically important for a broad range of applications spanning energy, defense, aviation, and aerospace. One of the most significant needs is for sensors that are capable of leak detection of H₂ at levels up to the lower explosive limit. Additional applications of hydrogen sensors requiring operation at elevated temperatures include monitoring of hydrogen in metallurgical processes as well as monitoring the composition of fuel gas streams in power generation technologies such as gas turbines and solid oxide fuel cells. Measurements of H₂ levels dissolved in transformer oil can also enable condition-based monitoring to provide early detection of potential failures with large associated economic and environmental impacts.
 

This patented technology establishes a novel method for concentrating rare earth elements (REEs) within coal byproducts to facilitate extraction processes. The technology is available for licensing and/or further collaborative research from the U.S. Department of Energy’s National Energy Technology Laboratory.

Challenge
REEs are essential components of modern technological devices, such as cell phones and computer hard drives, that support a broad range of vital industries. China provides the bulk of the world’s supply, largely due to environmental and economic challenges associated with extraction. Coal resources used in energy, iron, and steelmaking operations contain quantities of REEs sufficient to meet U.S. needs for years to come, but not as enriched solids. Cost-effective technology that facilitates the recovery of REEs in their most useful form offers the potential to simultaneously boost America’s economy, national security, and independence.

Research is active on the technology titled, "Controlling Au25 Charge State for Improved Catalytic Activity." This technology is available for licensing and/or further collaborative research from the U.S. Department of Energy’s National Energy Technology Laboratory.

Research is active on the development of regenerable bimetallic oxygen carriers for use in methane conversion to hydrogen combined with chemical looping combustion systems. This invention is available for licensing and/or further collaborative research from the U.S. Department of Energy’s National Energy Technology Laboratory.

Research is active on the design and synthesis of a new carbon dioxide (CO₂) capture solvent based on PEG-Siloxane. Unlike conventional gas-removal solvents, the NETL’s new solvent technology is hydrophobic and has a low vapor pressure. A hydrophobic solvent with low vapor pressure is highly advantageous because it can reduce the cost and energy-consumption associated with CO₂ capture by simplifying solvent regeneration and negating the need to remove water from fuel gas. For example, this solvent operates above room temperature and can be regenerated using low-grade and waste heat, whereas commercially available solvents operate below room temperature and can’t be regenerated using low-grade or waste heat This technology is available for licensing and/or further collaborative research from the U.S. Department of Energy’s National Energy Technology Laboratory.

The innovation represents a BIAS particle sorbent suspended in a non-aqueous fluid carrier (slurry) that is capable of CO₂ sorption, is easy to incorporate into established power plants, and can minimize energy and infrastructure requirements.

Challenge

Carbon sequestration can reduce the emissions of CO₂ from large point sources and holds potential to provide deep reductions in greenhouse gas emissions. Amine-based solid sorbents are effective and economical agents for CO₂ capture from gaseous mixtures. However, because of the high concentration of CO₂ in many feed streams, a large quantity of the gas often reacts with the sorbent exothermically to produce excessive heat, which must be removed from the sorbent to prevent temperature instability within the reactor and to eliminate potential degradation of the sorbent. Reducing the damage to sorbents with this technology and method can increase efficiency and reduce replacement costs faced by industries.

The U.S. Department of Energy’s National Energy Technology Laboratory (NETL) has developed a system and method for combining polyamines, which immobilizes the dye-absorbing amine sites within low cost, porous silica particles. The innovation has the potential to remove organic-based colorants and pollutants from different water sources. This invention is available for licensing and/or further collaborative research from NETL

Research is active on the development of metal ferrite oxygen carriers/catalysts for use in processes that convert carbon dioxide (CO₂) to carbon monoxide (CO) or synthesis gas by reforming or gasification. This invention is available for licensing and/or further collaborative research from the U.S. Department of Energy’s National Energy Technology Laboratory.

Challenge

A variety of approaches have been employed to harness CO₂ activation in order to produce useful products for chemical processes and to control greenhouse gas emissions. These approaches include catalytic dry reforming of methane, chemical looping dry reforming of fuel, and coal gasification with CO₂.

CO and synthesis gas are very useful precursors for various chemical processes and can be used as a fuel for energy production. In catalytic dry reforming, the production of syngas from CO₂ and methane is achieved in the presence of a catalyst that offers several advantages, such as mitigation of greenhouse gases emissions and conversion of CO₂ and methane into syngas which can be used to produce valuable downstream chemicals. In chemical looping dry reforming, oxygen from an oxygen carrier or metal oxide is used for partial combustion of methane or coal to produce syngas or CO. The reduced oxygen carrier is then oxidized using CO₂ to produce CO and oxidized oxygen carrier. In coal gasification with CO₂, production of syngas from coal is achieved through the reaction of coal with CO₂ instead of air or steam, which can be enhanced by the presence of metal oxide/metal promoters. Since the gasification process does not require steam, significant cost reductions would be expected. However, finding low-cost and efficient catalysts/oxygen carriers for these processes has been a major challenge, limiting their commercial success.

The U.S. Department of Energy’s National Energy Technology Laboratory (NETL) has developed a method for achieving tunable gas sensitivity of surface acoustic wave (SAW) devices. The innovation implements a class of materials with tunable absolute film conductivities called conducting metal oxides (CMOs), which enables SAW devices to be calibrated for gas sensitivity in diverse harsh-environment conditions.

The Department of Energy’s National Energy Technology Laboratory is seeking licensing partners interested in implementing United States Patent Number 6,908,497, titled "Solid Sorbents for Removal of Carbon Dioxide from Gas Streams at Low Temperatures."

Disclosed in this patent is a new low-cost carbon dioxide (CO₂) sorbent that can be used in large-scale gas-solid processes. Researchers have developed a new method to prepare these sorbents by treating substrates with an amine and/or an ether in a way that either one comprises at least 50 weight percent of the sorbent. The sorbent captures compounds contained in gaseous fluids through chemisorptions and/or physisorption between layers of the substrate lattice. The polar amine liquids are located within these layers. This method eliminates the need for high surface area supports and provides absorption capabilities independent of the sorbent surface area, and can be regenerated.