Electrocatalytically Upgrading Methane to Benzene in a Highly Compacted Microchannel Protonic Ceramic Membrane ReactorEmail PagePrint Page

Project Information

Prime Performer:Clemson University (Clemson, SC)Agreement Number:FE0031871
Project Duration:06/01/2020 - 05/31/2025Total Award Value:$1,250,000 
Technology Area:Natural Gas ConversionDOE Share:$1,000,000 
Key Technology:Performer Share:$250,000 

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Schematic description of HCM-PCMR
Schematic description of HCM-PCMR

Project Description

The overarching goal of this project is to develop a significantly process-intensified technology for methane dehydrogenation to aromatic (i.e., benzene) (MDA) in highly compacted microchannel protonic ceramic membrane reactors (HCM-PCMRs) by integrating multiple functions of single-atom catalysis, electrocatalysis, membrane catalysis, membrane separation, and advanced manufacturing.

Project Benefits

The major benefits of the proposed technology, as compared with state-of-art industrial GTL technology, are:

1) Highly intensified process: highly compacted catalytic membrane reactors.

2) Long term stability: less coke problem because of single-atom catalyst and small amount oxygen ion.

3) High benzene yield at a lower temperature: single-atom catalyst, membrane separation, and membrane catalysis.

4) High volumetric performance: microchannel design.

5) Isolated operation: co-production of electricity or hydrogen.

6) Flexible and cost-effective manufacturing: integrated additive manufacturing and laser process.

Contact Information

Federal Project Manager:David Cercone (david.cercone@netl.doe.gov)
Technology Manager:William Fincham (william.fincham@netl.doe.gov)
Principal Investigator:Joshua Tong (jianhut@clemson.edu)