NETL developed the process and invention to apply a specific energy source (radio frequency RF & microwave MW) to a specific electron emission material that will increase chemical reaction rates of gas phase chemistry for fuel reforming more than 10 times the rate of previous processes. The invention includes:

Materials that will provide a strong source of electrons to the gas phase of a chemical mixture that are both conductive and possess low energy electron surface states.

• A microwave or radio frequency source to enhance the dielectric constant of the electron source material. The microwave source will further reduce the electron surface state of the material increasing electron yield.
• The electron source material that can maintain an adjustable electric field that enhances electron emission and controls the emitted electron energy.

The invention provides a high-density source of electrons that will activate the oxygen in the reactant mixture. This form of low energy attachment is highly specific to electron energy. The lower the temperature and the higher the electron density at the required electron energy, the lower the energy requirements and size of the reactor system. This invention is designed to accomplish both.

Advantages

The invention is very specific. Although other reaction schemes to accomplish dry and partial oxidation reforming exist, none use the physics associated with this process. As noted, the invention, because of its unique approach, lowers the energy requirements of other processes and thus lowers the cost of production.